Production of high purity thorium oxide from complex ores leach liquor

Authors

Ayşe ERDEMFollow
Haydar GÜNEŞFollow
Çiğdem KARAFollow
Hasan AKÇAYFollow
Akan GÜLMEZFollow
Zümrüt ALKANFollow

DOI

10.19111/bulletinofmre.709316

Abstract

This paper investigates a method for separation and purification of thorium from leach liquors containing rare-earth elements (REE). Iron, which causes problems in the stage of thorium extracting, was first removed by using Adogen 464 solvent. Thorium was extracted with 30% D2EHPA-in kerosene with 1/3 organic/aqueous ratio and stoichiometry of the thorium-D2EHPA complex was calculated as 1:2.6 from slope analysis. After the extraction, LREE and HREE were scrubbed from the extracted organic with 0.25 M H₂SO₄ and 6 M HCl, respectively. Thorium oxalate was precipitated by oxalic acid and calcined at 1,050 °C. It was, after calcination, determined that purity of thorium oxide is 99.23%, based on the ICP-OES analysis..

https://doi.org/10.19111/bulletinofmre.709316

Recommended Citation

ERDEM, Ayşe; GÜNEŞ, Haydar; KARA, Çiğdem; AKÇAY, Hasan; GÜLMEZ, Akan; and ALKAN, Zümrüt (2023) "Production of high purity thorium oxide from complex ores leach liquor," Bulletin of the Mineral Research and Exploration: Vol. 2021: Iss. 164, Article 1.
DOI: https://doi.org/10.19111/bulletinofmre.709316